Departing from 'Arafat to Al-Muzdalifah. It is recommended to pray Maghrib and 'Isha together in Al-Muzdalifah on this night Sahih Muslim 1288 a

Arabic hadith text
وَحَدَّثَنِي حَرْمَلَةُ بْنُ يَحْيَى، أَخْبَرَنَا ابْنُ وَهْبٍ، أَخْبَرَنِي يُونُسُ، عَنِ ابْنِ شِهَابٍ، أَنَّأَخْبَرَهُ أَنَّ أَبَاهُ قَالَجَمَعَ رَسُولُ اللَّهِ صلى الله عليه وسلم بَيْنَ الْمَغْرِبِ وَالْعِشَاءِ بِجَمْعٍ لَيْسَ بَيْنَهُمَا سَجْدَةٌ وَصَلَّى الْمَغْرِبَ ثَلاَثَ رَكَعَاتٍ وَصَلَّى الْعِشَاءَ رَكْعَتَيْنِ ‏.‏فَكَانَ عَبْدُ اللَّهِ يُصَلِّي بِجَمْعٍ كَذَلِكَ حَتَّى لَحِقَ بِاللَّهِ تَعَالَى
Translation

Ubaidullah b. 'Abdullah b. 'Umar reported on the authority of his father (Allah be pleased with them) that Allah's Messenger (ﷺ) combined the sunset and 'Isha', prayers at Muzdalifa and there was no prostration (i. e. any rak'ahs of Sunan or Nawafil prayers) in between them. He observed three rak'ahs of the sunset prayer and two rak'ahs of the 'Isha' prayer, and 'Abdullah (b. 'Umar) observed the prayers in this very manner (at Muzdalifa) until he met his Lord.